Devulcanizing Algerian End-of-life Tire Rubber for Rubber Sustainability and Rubber Product Circular Economy, in Algeria
Abstract
Managing end-of-life tires (ELTs) remains a persistent global challenge for the transportation sector. Once discarded due to wear or irreparable damage, scrap tires pose severe environmental and health hazards. Although various disposal methods have been developed including landfilling, incineration, and crumb rubber production most are unsustainable and environmentally harmful. The vulcanization process, which transforms raw rubber into durable tire material, significantly hinders recycling efforts. However, recent technological advances offer promising solutions. In Algeria, over 6.2 million registered vehicles in 2020 generate more than six million scrap tires annually, with numbers expected to grow rapidly due to increasing vehicle ownership, shorter tire lifespans, and expanding electric and heavy-vehicle fleets. Without proper management, this waste will accumulate dramatically, exacerbating environmental degradation. Windsor Industrial Development Laboratory has developed an innovative devulcanization technology under the EcoCa™ brand, capable of reversing the vulcanization process effectively transforming used tire rubber back into a reusable form. This breakthrough enables the manufacturing of high-quality engineered rubber products. As a first application, the laboratory has successfully produced and tested passenger vehicle parking blocks made entirely from devulcanized rubber. The proposed four-step approach includes: i. Rubber recovery from scrap tires, ii. Devulcanization of the recovered rybber, iii. Compounding the devulcanized rubber, and iv. Manufacturing green products from recycled rubber. This technology offers multiple benefits: addressing environmental pollution, promoting rubber sustainability and circular economy, conserving natural resources, reducing energy consumption and greenhouse gas emissions, creating jobs, and building local technical expertise in Algeria. Windsor’s laboratory seeks industrial and academic partners in Algeria to establish a sustainable local recycling chain and support zero-waste manufacturing practices in the Rubber Industry.
Downloads
Metrics
References
Chouchaoui B. Devulcanization: A solution for scrap rubber. Rubber World . 2023 May;268(2):40.
Çataklı T, Erguder TH. Simultaneous devulcanization and denitrification: a novel approach for valorization of both ground tire rubber and nitrate-containing wastewater. Biodegradation. 2025;36(1):10. Available from: https://link.springer.com/journal/10532
Görbe Á, Kohári A, Halász-Kutasi IZ, Bárány T. Thermomechanical-chemical devulcanization of ground tire rubber. IOP Conf Ser Mater Sci Eng. 2024 Sep;1313(1):012008. Available from: https://iopscience.iop.org/article/10.1088/1757-899X/1313/1/012008
Rodak A, Haponiuk J, Wang S, Formela K. Investigating the combined effects of devulcanization level and carbon black grade on the SBR/GTR composites. Express Polym Lett. 2024 Dec;18(12):1191–208.
Parsamanesh M, Abbassi-Sourki F, Karrabi M, Soltani S. Thermomechanical devulcanization of butyl rubber using twin-screw extruder: Process parameters, viscoelastic and compatibility properties. Prog Rubber Plast Recycl Technol . 2024 Aug;40(3):245–67.
Roetman E, Joustra J, Heideman G, Balkenende R. Does the Rubber Meet the Road? Assessing the Potential of Devulcanization Technologies for the Innovation of Tire Rubber Recycling. Sustainability. 2024 Apr;16(7):2900. Available from: https://www.mdpi.com/2071-1050/16/7/2900
Lewandowski A, Candau N, Maspoch ML. Tensile and Elastocaloric Properties of Natural/Devulcanized Waste Rubber Blends. Macromol Rapid Commun . 2024 Nov;45(21):e2400422. Available from: https://onlinelibrary.wiley.com/doi/full/10.1002/marc.202400422
Colom X, Saeb MR, Cañavate J. Microstructural phenomena in ground tire rubber (GTR) devulcanized via combined thermochemomechanical and microwave processes monitored by FTIR and DTGA assisted by other techniques. Express Polym Lett. 2024 Sep;18(9):950–61. Available from: https://epolymerscience.com/
Danila V, Januševičius T. Adsorption of aqueous Pb(II) using non-devulcanized and devulcanized tyre rubber powder: a comparative study. Environ Sci Pollut Res Int. 2024 Jun;31(28):39867–83. Available from: https://link.springer.com/journal/11356
Colom X, Farrés L, Mujal R, Wang S, Cañavate J. Analyzing Thermal Degradation Effects on Devulcanized GTR-Based NR/SBR/NBR Rubber Compounds Reinforced with SiO₂ Particles. Polymers. 2024 Nov;16(23):3270. Available from: https://www.mdpi.com/2073-4360/16/23/3270
Ghosh R, Mani C, Krafczyk R, Schnell R, Talma A, Blume A, et al. Exploring the Impact of Reinforcing Filler Systems on Devulcanizate Composites. Polymers. 2024 May;16(11):1448. Available from: https://www.mdpi.com/2073-4360/16/11/1448
Kędzia J, Haponiuk J, Formela K. Natural Rubber Latex Wastes from Balloon Production as Valuable Source of Raw Material: Processing, Physico-Mechanical Properties, and Structure. J Compos Sci . 2024 Sep;8(9):365. Available from: https://www.mdpi.com/2504-477X/8/9/365
Guo L, Bai L, Zhao J, Liu K, Jian X, Chai H, et al. Enhancing Devulcanizing Degree and Efficiency of Reclaimed Rubber by Using Alcoholic Amines as the Devulcanizing Agent in Low-Temperature Mechano-Chemical Process. Polymers. 2024 Jan;16(3):395. Available from: https://www.mdpi.com/2073-4360/16/3/395
Obukhova S, Budkina A, Korolev E, Gladkikh V. Impacts of Waste Rubber Products on the Structure and Properties of Modified Asphalt Binder: Part I-Crumb Rubber. Materials. 2024 Sep;17(19):4685. Available from: https://www.mdpi.com/1996-1944/17/19/4685
Kohári A, Bárány T. Sustainable thermoplastic elastomers based on thermoplastic polyurethane and ground tire rubber. J Appl Polym Sci. 2024 Nov;141(44). Available from: https://onlinelibrary.wiley.com/doi/abs/10.1002/app.56410
Akkenzheyeva A, Haritonovs V, Bussurmanova A, Merijs-Meri R, Imanbayev Y, Serikbayeva A, et al. The Use of Rubber-Polymer Composites in Bitumen Modification for the Disposal of Rubber and Polymer Waste. Polymers. 2024 Nov;16(22):3177. Available from: https://www.mdpi.com/2073-4360/16/22/3177
Colom X, Sans J, de Bruijn F, Carrillo F, Cañavate J. Structural, Thermal and Mechanical Assessment of Green Compounds with Natural Rubber. Macromol. 2024 Sep;4(3):566–81. Available from: https://www.mdpi.com/2624-7721/4/3/566
Hejna A, Kosmela P, Olszewski A, Zedler Ł, Formela K, Skórczewska K, et al. Management of ground tire rubber waste by incorporation into polyurethane-based composite foams. Environ Sci Pollut Res Int . 2024 Mar;31(12):17591–616. Available from: https://link.springer.com/article/10.1007/s11356-023-03007-z
Rosales C, Hocine NA, Bernal C, Pettarin V. Toughness improvement of LLDPE/PP blend by incorporation of GTR waste. Polym Bull. 2024 Jun;81(8):6743–60. Available from: https://link.springer.com/article/10.1007/s00289-023-04775-3
Ghosh R, Mani C, Krafczyk R, Schnell R, Paasche A, Talma A, et al. New Route of Tire Rubber Devulcanization Using Silanes. Polymers. 2023 Jun;15(13):2848. Available from: https://www.mdpi.com/2073-4360/15/13/2848
Mondal D, Hait S, Ghorai S, Wießner S, Das A, De D, et al. Back to the origin: A spick-and-span sustainable approach for the devulcanization of ground tire rubber. J Vinyl Addit Technol . 2023 Mar;29(2):240–58. Available from: https://onlinelibrary.wiley.com/doi/abs/10.1002/vnl.21963
Zhang Y, Fan X, Zhao Z, Wang Y, Chen Y, Li H, et al. Enhanced mechanical properties and thermal stability of reclaimed rubber composites through silane coupling agents. Polymers. 2023 Jan;15(1):101. Available from: https://www.mdpi.com/2073-4360/15/1/101
Liu Y, Sun M, Zhang W, Zhou L. Devulcanization of waste tire rubber using supercritical CO₂-assisted microwave treatment. Waste Manag. 2023 Feb;157:123–32. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0956053X2200789X
Li Q, Xu H, Wu T, Huang F. Preparation and characterization of modified bitumen with waste tire rubber and nanoclay. Constr Build Mater. 2023 Apr;373:130582. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0950061823002115
Yang X, Zhang J, Wang K. Mechanical performance and durability of crumb rubber-modified asphalt mixtures under freeze-thaw cycles. J Clean Prod. 2023 May;403:136631. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0959652623010217
Magagula V, Mamba B, Msagati T. Advances in pyrolysis and devulcanization technologies for tire recycling: A review. Renew Sustain Energy Rev. 2023 Jun;181:113210. Available from: https://linkinghub.elsevier.com/retrieve/pii/S1364032123002014
Zhao L, Hu C, Lin H, Chen J. Effect of organomodified montmorillonite on the devulcanization efficiency and properties of recycled rubber. Appl Clay Sci. 2023 Mar;229:106812. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0169131723000318
Ketov AA, Karpacheva GP, Petrov AV. Chemical modification of waste tire rubber by organic solvents and its application in bituminous binders. Fuel. 2023 Apr;337:126734. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0016236122024563
Singh R, Kumar A, Sharma N. Thermal degradation behavior of devulcanized rubber blends: Kinetic analysis and thermodynamic parameters. Thermochim Acta. 2023 Feb;720:106–72. Available from: https://linkinghub.elsevier.com/retrieve/pii/S004060312200311X
Patel K, Shah R, Desai A. Influence of particle size and surface treatment on mechanical properties of ground tire rubber-reinforced polyurethane composites. J Appl Polym Sci. 2023 May;140(19):51989. Available from: https://onlinelibrary.wiley.com/doi/abs/10.1002/app.51989
Almeida JR, Ferreira PM, Costa LN. Use of waste tire rubber as a partial replacement for coarse aggregate in concrete pavements. Case Stud Constr Mater. 2023 Apr;18:e01876. Available from: https://linkinghub.elsevier.com/retrieve/pii/S2214509523000321
Kim H, Park S, Lee J. Performance evaluation of rubberized asphalt mixtures incorporating warm-mix additives. Int J Pavement Eng. 2023 Mar;24(3):210–20. Available from: https://www.tandfonline.com/doi/full/10.1080/10298436.2022.2041122
Rodak A, Susik A, Kowalkowska-Zedler D, Zedler Ł, Formela K. Crosslinking, Morphology, and Physico-Mechanical Properties of GTR/SBS Blends: Dicumyl Peroxide vs. Sulfur System. Materials. 2023 Mar;16(7):2807. Available from: https://www.mdpi.com/1996-1944/16/7/2807
Leong SY, Lee SY, Koh TY, Ang DTC. 4R of rubber waste management: Current and outlook. J Mater Cycles Waste Manag. 2023 Jan;25(1):37–51. Available from: https://link.springer.com/article/10.1007/s10163-022-01509-7
Yan X, Guo Y, Zhang Y, Lu C. Microwave-assisted devulcanization of waste tire rubber: Process optimization and product characterization. J Environ Chem Eng. 2023 Apr;11(2):109476. Available from: https://linkinghub.elsevier.com/retrieve/pii/S221334372201476X
Hassan MK, El-Sayed SA, Ahmed AM. Environmental impact assessment of different tire recycling methods: A comparative life cycle study. Waste Manage. 2023 Mar;158:215–25. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0956053X22009012
Bianchi O, Pereira PB, Ferreira CA. Mechanochemical Treatment in High-Shear Thermokinetic Mixer as an Alternative for Tire Recycling. Polymers. 2022 Oct;14(20):4419. Available from: https://www.mdpi.com/2073-4360/14/20/4419
Wiśniewska P, Wang S, Formela K. Waste tire rubber devulcanization technologies: State-of-the-art, limitations and future perspectives. Waste Manag. 2022 Aug;150:174–84. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0956053X22004430
Wang Y, Li Z, Zhang X. Application of waste tire rubber in green construction materials: A review. J Clean Prod. 2022 Jul;356:131634. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0959652622013211
Kirshanov VA, Ivanov DS, Petrov AA. Glycolysis-based recycling of polyester tire cord and simultaneous devulcanization of chloroprene rubber. Polym Degrad Stab. 2022 Sep;191:109987. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0141391022002113
Gumede NS, Onyango MS, Ndlovu S. Thermo-chemical devulcanization of waste tires in supercritical CO₂ with organic agents. J Supercrit Fluids. 2022 Dec;190:105678. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0896844622001895
Wang Z, Liu H, Pan C. High-quality ground tire rubber production via supercritical CO₂ jet pulverization. Powder Technol. 2022 Nov;409:117723. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0032591022006339
Kalin M. Industrial-scale process for high-quality rubber recovery from waste tires: A patented scalable devulcanization method. Rubber World. 2022 Apr;267(1):12–20. Available from: https://www.rubberworld.com/
Liu J, Chen F, Li X. Sustainable utilization of waste tire rubber in thermoplastic elastomers: Processing and performance evaluation. Express Polym Lett. 2022 Jun;16(6):587–600. Available from: https://epolymerscience.com/
Zhang W, Zhao Y, Sun H. Influence of filler type on mechanical and thermal properties of devulcanized rubber composites. Compos Part B Eng. 2022 Oct;244:120178. Available from: https://linkinghub.elsevier.com/retrieve/pii/S1359836822006112
Ruikun D, Huifang Y, Mengzhen Z, Wang H. Preparation of Asphalt Modifier Made of Waste Tire Crumb Rubber and Waste Cooking Oil. J Mater Civ Eng. 2022 Aug;34(8):04022178. Available from: https://ascelibrary.org/doi/10.1061/%28ASCE%29MT.1943-5533.0004271
Elnaggar MY, Fathy ES, Okasha R. Character alteration of SBR via compounding with ultrasonically and mechanochemically devulcanized rubber influenced by gamma irradiation in presence of polyester fibers. Polym Bull . 2022 Nov;79(11):9859–80. Available from: https://link.springer.com/article/10.1007/s00289-022-04123-w
Wiśniewska P, Zedler Ł, Marć M, Klein M, Haponiuk J, Formela K. Ground Tire Rubber Modified by Elastomers via Low-Temperature Extrusion Process: Physico-Mechanical Properties and Volatile Organic Compounds Emission Assessment. Polymers. 2022;14(3):546. Available from: https://www.mdpi.com/2073-4360/14/3/546
Xiao Z, Pramanik A, Basak AK, Prakash C, Shankar S. Material recovery and recycling of waste tyres—A review. Cleaner Mater. 2022 Sep;5:100115. Available from: https://linkinghub.elsevier.com/retrieve/pii/S2666686522000379
Khan SU, Ahmad I, Haider W. Recent advances in chemical devulcanization of waste tire rubber: Mechanisms, reagents and challenges. J Hazard Mater. 2022 Oct;437:129312. Available from: https://linkinghub.elsevier.com/retrieve/pii/S0304389422010215
Krasnovskikh MP, Chudinov SY, Sliusar NN, Pugin KG, Vaisman YI. Production of a nanostructured bitumen modifier in the reprocessing of automobile tires. Nanotehnologii v stroitelʹstve. 2022 Jan;14(6):501–9. Available from: https://www.nano-building.ru/
Karabork F. Investigation of the mechanical, tribological and corrosive properties of epoxy composite coatings reinforced with recycled waste tire products. Express Polym Lett. 2022 Nov;16(11):1114–27. Available from: https://epolymerscience.com/
El-Nemr KF, Ali MA, Gad YH. Manifestation of the silicate filler additives and electron beam irradiation on properties of SBR/devulcanized waste tire rubber composites for floor tiles applications. Polym Compos. 2022 Jan;43(1):366–77. Available from: https://onlinelibrary.wiley.com/doi/abs/10.1002/pen.25843
Żukowska W, Kosmela P, Wojtasz P, Szczepański M, Piasecki A, Barczewski R, et al. Comprehensive Enhancement of Prepolymer-Based Flexible Polyurethane Foams’ Performance by Introduction of Cost-Effective Waste-Based Ground Tire Rubber Particles. Materials. 2022 Aug;15(16):5728. Available from: https://www.mdpi.com/1996-1944/15/16/5728
Makoundou C, Johansson K, Wallqvist V, Sangiorgi C. Functionalization of Crumb Rubber Surface for the Incorporation into Asphalt Layers of Reduced Stiffness: An Overview of Existing Treatment Approaches. Recycling. 2021 Mar;6(1):19. Available from: https://www.mdpi.com/2313-4321/6/1/19
Zedler Ł, Colom X, Cañavate J, Formela K. GTR/NBR/Silica Composites Performance Properties as a Function of Curing System: Sulfur versus Peroxides. Materials. 2021 Sep;14(18):5345. Available from: https://www.mdpi.com/1996-1944/14/18/5345
Wiśniewska P, Zedler Ł, Formela K. Processing, Performance Properties, and Storage Stability of Ground Tire Rubber Modified by Dicumyl Peroxide and Ethylene-Vinyl Acetate Copolymers. Polymers. 2021 Nov;13(22):4014. Available from: https://www.mdpi.com/2073-4360/13/22/4014
Marín-Genescà M, Mujal-Rosas R, García-Amorós J, Mudarra M, Ramis-Juan X, Colom X. Study Analysis of Thermal, Dielectric, and Functional Characteristics of an Ethylene Polyethylene Diene Monomer Blended with End-of-Life Tire Microparticles Amounts. Polymers. 2021 Feb;13(4):509. Available from: https://www.mdpi.com/2073-4360/13/4/509
Allan KM, Bedzo OKK, van Rensburg E, Görgens JF. The Microbial devulcanisation of Waste Ground Tyre Rubber Using At. ferrooxidans DSMZ 14,882 and an Unclassified Sulphur-Oxidising Consortium. Waste Biomass Valoriz. 2021 Dec;12(12):6659–70. Available from: https://link.springer.com/article/10.1007/s12649-021-01423-8
Araujo-Morera J, Verdugo-Manzanares R, González S, Verdejo R, Lopez-Manchado MA, Hernández Santana M. On the Use of Mechano-Chemically Modified Ground Tire Rubber (GTR) as Recycled and Sustainable Filler in Styrene-Butadiene Rubber (SBR) Composites. J Compos Sci. 2021;5(3):68. Available from: https://www.mdpi.com/2504-477X/5/3/68
Halász IZ, Kocsis D, Simon DA, Kohári A, Bárány T. Development of Polypropylene-based Thermoplastic Elastomers with Crumb Rubber by Dynamic Vulcanization: A Potential Route for Rubber Recycling. Period Polytech Chem Eng. 2020;64(2):248–54. Available from: https://pp.bme.hu/ch/article/view/14882
Raslan HA, Fathy ES, Abdel Aal SE. Thermal aging and automotive oil effects on the performance of electron beam irradiated styrene butadiene rubber/waste and microwave devulcanized rubber blends. Prog Rubber Plast Recycl Technol. 2023 Feb;39(1):40–63. Available from: https://journals.sagepub.com/doi/full/10.1177/14777606221148345
Ketov AA, Krasnovskikh MP, Kalinina EV, Ofrikhter VG, Tatiannikov DA. Influence of a nanostructural modifier from automobile tires on consumer properties of bitumen. Nanotehnologii v stroitelʹstve. 2023 Jan;15(3):267–73. Available from: https://www.nano-building.ru/
Pérez-Campos R, Fayos-Fernández J, Monzó-Cabrera J, Martín Salamanca F, López Valentín J, Catalá-Civera JM, et al. Dynamic Permittivity Measurement of Ground-Tire Rubber (GTR) during Microwave-Assisted Devulcanization. Polymers. 2022 Aug;14(17):3543. Available from: https://www.mdpi.com/2073-4360/14/17/3543
Leong SY, Lee SY, Koh TY, Ang DTC. 4R of rubber waste management: Current and outlook. J Mater Cycles Waste Manag. 2023 Jan;25(1):37–51. Available from: https://link.springer.com/article/10.1007/s10163-022-01509-7
Rodak A, Susik A, Kowalkowska-Zedler D, Zedler Ł, Formela K. CrossLinking, Morphology, and Physico-Mechanical Properties of GTR/SBS Blends: Dicumyl Peroxide vs. Sulfur System. Materials. 2023 Mar;16(7):2807. Available from: https://www.mdpi.com/1996-1944/16/7/2807
Xiao Z, Pramanik A, Basak AK, Prakash C, Shankar S. Material recovery and recycling of waste tyres—A review. Cleaner Mater. 2022 Sep;5:100115. Available from: https://linkinghub.elsevier.com/retrieve/pii/S2666686522000379
Wiśniewska P, Zedler Ł, Marć M, Klein M, Haponiuk J, Formela K. Ground Tire Rubber Modified by Elastomers via Low-Temperature Extrusion Process: Physico-Mechanical Properties and Volatile Organic Emission Assessment. Polymers. 2022 Jan;14(3):546. Available from: https://www.mdpi.com/2073-4360/14/3/546
Fazli A, Rodrigue D. Recycling Waste Tires into Ground Tire Rubber (GTR)/Rubber Compounds: A Review. J Compos Sci . 2020;4(3):103. Available from: https://www.mdpi.com/2504-477X/4/3/103
Zedler Ł, Burger P, Wang S, Formela K. Ground Tire Rubber Modified by Ethylene-Vinyl Acetate Copolymer: Processing, Physico-Mechanical Properties, Volatile Organic Compounds Emission and Recycling Possibility. Materials. 2020 Oct;13(20):4669. Available from: https://www.mdpi.com/1996-1944/13/20/4669
Danila V, Januševičius T. Adsorption of aqueous Pb(II) using non-devulcanized and devulcanized tyre rubber powder: a comparative study. Environ Sci Pollut Res Int. 2024 Jun;31(28):39867–83. Available from: https://link.springer.com/article/10.1007/s11356-023-03007-z
Ghosh R, Mani C, Krafczyk R, Schnell R, Paasche A, Talma A, et al. New Route of Tire Rubber Devulcanization Using Silanes. Polymers. 2023 Jun;15(13):2848. Available from: https://www.mdpi.com/2073-4360/15/13/2848
Obukhova S, Budkina A, Korolev E, Gladkikh V. Impacts of Waste Rubber Products on the Structure and Properties of Modified Asphalt Binder: Part I-Crumb Rubber. Materials. 2024 Sep;17(19):4685. Available from: https://www.mdpi.com/1996-1944/17/19/4685
Kohári A, Bárány T. Sustainable thermoplastic elastomers based on thermoplastic polyurethane and ground tire rubber. J Appl Polym Sci . 2024 Nov;141(44). Available from: https://onlinelibrary.wiley.com/doi/abs/10.1002/app.56410
Akkenzheyeva A, Haritonovs V, Bussurmanova A, Merijs-Meri R, Imanbayev Y, Serikbayeva A, et al. The Use of Rubber-Polymer Composites in Bitumen Modification for the Disposal of Rubber and Polymer Waste. Polymers. 2024 Nov;16(22):3177. Available from: https://www.mdpi.com/2073-4360/16/22/3177
Copyright (c) 2025 Benabdallah Chouchaoui

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.


